Research Advances of the Chiral Binap-Ru(II) Catalysts in Asymmetric Hydrogenation Reactions
CHINESE JOURNAL OF ORGANIC CHEMISTRY(2017)
摘要
Chiral 2,2'-bis(diphenylphosphino)-1,1'-binapthyl (Binap) ligand consists of a pair of 2-diphenylphosphinonaphthyl groups connected at the 1 and 1' positions, being of the nature of the C-2-axial chirality with optical activity of +/- 234 degrees. The Binap can coordinate with many transitional metals to form stable chelation complexes, effecting the chirality transfer to the metal center for function in asymmetrically catalytic reactions. This contribution is focused on the Binap-Ru(II) catalytic system that covers the various substrates, reaction conditions, enantioselectivity of the products, reaction mechanism, and others on the basis of the prepared stable Binap-Ru(II) complexes as the clue in the text. This study will give a deep understanding of this system especially concerning the applied catalytic synthesis of the useful organic molecules.
更多查看译文
关键词
Binap ligand,chiral ruthenium complexes,asymmetric catalysis,reaction mechanism,application
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要