Redox Targeting-Based Thermally Regenerative Electrochemical Cycle Flow Cell for Enhanced Low-Grade Heat Harnessing.
Elements(2021)
摘要
A large amount of low-grade heat (<100 degrees C) is produced in electrical devices and mostly wasted. This type of heat without effective dissipation also causes compromised device performance, reliability, and lifespan. To tackle these issues, a redox targeting (RT)-based flow cell with judiciously designed thermoelectrically active redox materials is demonstrated for the first time for efficient heat-to-electricity conversion through a thermally regenerative electrochemical cycle (TREC). Compared with the conventional TREC systems, the RT-based flow cell not only reveals considerably enhanced thermoelectric efficiency, but the flow of redox fluids also provides a cooling function to the system. In this work, solid material Ni0.2Co0.8(OH)(2) and redox mediator [Fe(CN)(6)](4-/3-), both of which have negative temperature coefficient and share identical redox potential, are paired via RT-reactions to boost the capacity and meanwhile thermoelectric efficiency of a [Fe(CN)(6)](4-/3-)/Zn0/2+-based flow cell. Upon operating over the TREC cycle, the RT-based flow cell converts heat to electricity at an unprecedented absolute thermoelectric efficiency of 3.61% in the temperature range of 25-55 degrees C.
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关键词
low‐,grade heat harnessing,redox flow batteries,redox targeting,thermally regenerative electrochemical cycles
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