Spectroscopic investigations and magnetic measurements on iron-containing barium titanate glass-ceramics

Ruzha Harizanova,Ivalina Avramova,Zara Cherkezova-Zheleva,Daniela Paneva,Rositsa Kukeva,Radostina Stoyanova,Ivailo Gugov,Irena Mihailova,Dimitar Tzankov,Milena Georgieva,Georgi Avdeev,Christian Bocker,Christian Rüssel

Journal of Non-Crystalline Solids（2020）

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摘要

•XPS shows Fe3+ in tetrahedral and octahedral coordinations.•EPR proves four types non-homogeneously distributed Fe3+ ions.•Mössbauer spectroscopy shows Fe3+ in tetrahedral and octa/pentahedral coordinations.•VSM reveals ferromagnetic properties of selected glass-ceramics.

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关键词

Barium titanate glass-ceramics,Iron,Electron paramagnetic resonance spectroscopy,X-ray photoelectron spectroscopy,Mössbauer spectroscopy,Magnetometry

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