Rhenium borides (Re3B and ReB2) mechanosynthesis and their use as a catalyst for H2 production from biomass pyrolysis

M.G. Granados-Fitch, J.M. Quintana-Melgoza,E.A. Juarez-Arellano,M. Avalos-Borja

Materials Research Bulletin（2021）

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摘要

•Re3B mechanosynthesis is reported for the first time.•ReB2 and Re3B are used in catalytic H2 production by CS pyrolysis.•800 °C and 10 wt % of catalyst are the optimal values to enhance H2 production.•Re3B reaches 77.4 % H2 yield at optimal conditions.•A mechanism for H2 formation is proposed from CS pyrolysis.

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关键词

A: Inorganic compounds,B: Chemical synthesis,C: X-ray diffraction,C: Infrared spectroscopy,D: Catalytic properties

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