Synthesis and structural characterisation of some mononuclear 1:1:1 complexes of coinage metal(I) compounds with tertiary phosphines (arsines) and 1,2-diamines, [MX(EPh3)(N,N'-1,2-diamine)]

Corrado di Nicola,Effendy,Robert D. Hart,Fabio Marchetti,Claudio Pettinari,Riccardo Pettinari,Brian W. Skelton,Allan H. White

Inorganica Chimica Acta（2021）

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摘要

•Synthesis of coinage metal complexes in 1,2-diamines as solvent.•1:1:1 complexes of silver and copper with phosphine and 1,2 diamine ligands.•Structure determination of mixed-ligands Cu and Ag complexes.•Comparison of structural parameters in [M(N2-donor)(P-donor)X] complexes (M = Ag, Cu).

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关键词

Silver,Copper,Phosphine,Diamines,X-ray,NMR

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Synthesis and structural characterisation of some mononuclear 1:1:1 complexes of coinage metal(I) compounds with tertiary phosphines (arsines) and 1,2-diamines, [MX(EPh3)(N,N&#x27;-1,2-diamine)]

Synthesis and structural characterisation of some mononuclear 1:1:1 complexes of coinage metal(I) compounds with tertiary phosphines (arsines) and 1,2-diamines, [MX(EPh3)(N,N'-1,2-diamine)]