Expedient Organocatalytic Aza-Morita–Baylis–Hillman Reaction Through Ball-Milling
ACS sustainable chemistry & engineering(2020)
摘要
A ball-milling enabled tertiary amine catalyzed aza-Morita–Baylis–Hillman reaction is reported. The reaction process does not require solvent, has significantly shorter reaction times than previous methods and is reported on a range of imines and acrylate Michael acceptors across than 26 examples. A 12-fold scaled-up example is also reported as well as experimental comparisons to solution-based experiments and neat-stirred reactions.
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关键词
Mechanochemistry,Organocatalysis,Metal-free,Solvent-free,Reaction methodology
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