Group IV Metal Dimethylamido Complexes of the Chiral Cyclopentadienyl‐type Ligand (Cp C ) –1

Florian Nährig,Sergej Lauk,Yu Sun,Helmut Sitzmann,Werner. R. Thiel

Zeitschrift für anorganische und allgemeine Chemie（2020）

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摘要

Trisdimethylamido complexes of the Group IV elements titanium, zirconium and hafnium bearing the chiral Cp-type ligand (Cp-C)(-1) were synthesized and characterized by means of NMR spectroscopy, elemental analysis and single crystal X-rax diffraction.

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关键词

Group IV elements, Cyclopentadienyl complexes, Bulky ligand, Chiral ligand, Half sandwich complexes

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