IMC Growth and Mechanical Properties of Cu/In-48Sn/Cu Solder Joints

JOURNAL OF ELECTRONIC MATERIALS(2021)

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摘要
The growth and shear properties of intermetallic compound (IMC) in Cu/In-48Sn/Cu solder joints at different bonding times have been studied, and the growth kinetics of interfacial Cu 3 (In,Sn) phase at different bonding temperatures investigated. The results show that the IMC of the Cu/In-48Sn/Cu joint is composed of Cu 6 (In,Sn) 5 and Cu 3 (In,Sn) but transforms to Cu 3 (In,Sn) after 120 min of bonding at 260°C and pressure of 3 MPa. The morphology of the Cu 6 (In,Sn) 5 layer changed from flat to scallop, and the growth rate of Cu 3 (In,Sn) located directly below the convex part of the Cu 6 (In,Sn) 5 sector was significantly higher than that of Cu 3 (In,Sn) located directly below the concave part of the Cu 6 (In,Sn) 5 sector. The shear strength of the solder joints first increased then slowly decreased, reaching 21.8 MPa when increasing the bonding time to 60 min. The shear strength of the solder joints was improved by the formation of Cu 6 (In,Sn) 5 and Cu 3 (In,Sn), and Cu 3 (In,Sn) phase played a greater role in improving the shear strength of the solder joints than did Cu 6 (In,Sn) 5 phase. The growth kinetics index n of Cu 3 (In,Sn) was 0.478 to 0.495, and the growth mechanism of Cu 3 (In,Sn) was controlled by diffusion at bonding temperatures of 250°C to 280°C.
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关键词
Transient liquid-phase bonding,In-48Sn solder,interface growth,shear property
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