From semi-metal to superconductor: The New Mo12 Cluster Sulfides Rb1+xMo12S14 (x = 0.08, and 1.65)

Journal of Alloys and Compounds（2021）

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摘要

•Large one-dimensional channel crystal structure.•RbxMo12S14 compounds are particularly well adapted for topotactic reactions by soft chemistry or electrochemistry.•Evolution of the electrical resistivity with the Rb stoichiometry•Superconductor.

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关键词

Reduced molybdenum sulfide,Molybdenum clusters,Tunnelled structure,Soft chemistry,Cationic mobility,Resistivity measurement,Superconductor

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From semi-metal to superconductor: The New Mo12 Cluster Sulfides Rb1+xMo12S14 (x = 0.08, and 1.65)

From semi-metal to superconductor: The New Mo12 Cluster Sulfides Rb1+xMo12S14 (x = 0.08, and 1.65)