Spin-dependent magnetism and superparamagnetic contribution to the magnetocaloric effect of non-stoichiometric manganite nanoparticles

APPLIED MATERIALS TODAY(2022)

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摘要
•La0.8-x□xNa0.2Mn1+xO3-Δ with strong spin-electron coupling has been prepared.•Well-developed crystalline spherical-like nanoparticles contain MnB3+, MnB4+, MnA2+.•Spin-dependent magnetism is observed due to eg-electron localization–delocalization.•Multicomponent nonlinear magnetic system shows complex critical behaviour near TC.•Superparamagnetic contribution of nanoparticles to magnetocaloric effect was found.
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关键词
Point defects, Nanoparticles, Spin, Magnetism, Entropy, Magnetocaloric effect
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