Trans-stereochemistry from the insertion of alkynes into a ruthenium - carbon bond of a bridging-phenyl ligand

Journal of Organometallic Chemistry(2021)

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摘要
•Insertion of alkynes into metal – phenyl bond yields alkenyl ligands with trans-stereochemistry.•Ru5Au clusters have bridging alkenyl ligands with σ+π-coordination.•Crystal structure characterizations of bridging alkenyl ligands.
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关键词
Alkyne-insertion,Trans-stereochemistry,Ruthenium,Cluster,Crystal structure
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