The Mechanism Behind Enhanced Reactivity of Unsaturated Phosphorus(v) Electrophiles Towards Thiols

Yerin Park, Alice L. Baumann, Hyejin Moon,Stephen Byrne,Marc-Andre Kasper,Songhwan Hwang,Han Sun,Mu-Hyun Baik,Christian P. R. Hackenberger

Chemical science（2021）

引用 8|浏览21

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摘要

Computational analysis of different unsaturated phosphorus(v) electrophiles revealed a mechanistic picture to rationalize their selectivity and reactivity in cysteine-selective peptide and protein modifications.

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