Assembling Triazolated Calix[4]semitubes by Means of Copper(i)-Catalyzed Azide–alkyne Cycloaddition

Alexander Gorbunov,Nikolay Ozerov,Maria Malakhova, Artur Eshtukov,Dmitry Cheshkov,Stanislav Bezzubov,Vladimir Kovalev,Ivan Vatsouro

Organic chemistry frontiers（2021）

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摘要

Calix[4]arene-based bis(alkynes) and bis(azides) react with each other under thoroughly tuned CuAAC conditions and produce diverse biscalixarene semitube assemblies linked by two triazole units, which are capable of binding transition metal cations.

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