Phio-Mediated Oxidative Dethioacetalization/Dethioketalization Under Waterfree Conditions
ARKIVOC(2021)
摘要
Treatment of thioacetals and thioketals with iodosobenzene in anhydrous DCM conveniently afforded the corresponding carbonyl compounds in high yields under water-free conditions. The mechanistic studies indicate that this dethioacetalization/dethioketalization process does not need water and the oxygen of the carbonyl products comes from the hypervalent iodine reagent.[GRAPHICS]
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关键词
Iodosobenzene, thioacetal, thioketal, dethioacetalization, carbonyl compound, hypervalent iodine reagent
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