Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions.

Marjan Hosseinzadeh,Sergio Sanz,Jan van Leusen,Natalya V Izarova,Euan K Brechin,Scott J Dalgarno,Paul Kögerler

Chemical communications (Cambridge, England)（2021）

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摘要

Combination of phosphoryl and calix[4]arene moieties in the same organic framework (LPO) directs the formation of homoleptic double-decker complexes [LnIII(LPO)2](OTf)3 for Ln = Tb and Dy, with the latter displaying slow relaxation of the magnetisation.

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