Bis(5-Amino-2-Chlorobenzoato-Kappa O)Triphenylantimony(V)

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE(2009)

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摘要
In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C-H center dot center dot center dot O interactions occur. The molecules are connected by intermolecular N-H center dot center dot center dot O, N-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen-bonding interactions and C-H center dot center dot center dot pi stacking interactions, forming a three-dimensional supramolecular framework
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