Thermomagnetic Generation Performance Of Gd And La(Fe, Si)(13)H-Y/In Material For Low-Grade Waste Heat Recovery

ADVANCED SUSTAINABLE SYSTEMS(2021)

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摘要
The recovery of waste heat is urgently required to solve challenging energy and environmental issues. Thermomagnetic generation (TMG) technology using magnetic phase transition materials can realize the conversion of low-grade waste heat into electrical energy. However, efficient TMG materials hold the key to the development of this technology. Herein, the TMG performance of La(Fe, Si)(13)H-y/In is studied in comparison with the benchmark material Gd systematically. The induced current I is related to the change rate of the average magnetization over time dM/dt according to Faraday's law. In addition, the location of T-C in the working temperature range is an important factor affecting TMG performance. Due to the sharper magnetic transition, La(Fe, Si)(13)H-y/In presents a maximum intrinsic I of 9.12 mu A g(-1), approximate to 90% higher than that of Gd (4.82 mu A g(-1)). Moreover, the average output electrical power density and cost performance of La(Fe, Si)(13)H-y/In are 0.42 mW m(-3) and 0.102 nW USD-1, which are also significantly higher than those of Gd, 0.10 mW m(-3) and 0.005 nW USD-1, respectively. In comparison with Gd, the present work suggests that the La(Fe, Si)(13)H-y/In possesses much higher potential in the field of low-grade waste heat recovery.
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关键词
La(Fe, Si)(13), magnetocaloric effect, thermomagnetic generators
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