Fluorination Of Alpha-Diazo-Gamma-Lactams With The Olah Reagent

Alexander Kazantsev,Daniil Zhukovsky,Andrey Bubyrev,Dmitry Dar'In,Mikhail Krasavin

TETRAHEDRON LETTERS（2021）

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摘要

A series of N-aryl alpha-fluoro-gamma-lactams were successfully prepared by hydrofluorination of diazo counterparts with the Olah reagent in moderate yields. This approach was also applied to bromofluorination with N-bromosuccinimide as electrophilic bromine source. (C) 2021 Elsevier Ltd. All rights reserved.

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关键词

N-aryl 2-pyrrolidones, alpha-Fluorination of carbonyl compounds, Diazo compounds, The Olah reagent

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