On the fluxional behaviour of the cluster [Ir4(CO)11PEt3]

Inorganica Chimica Acta（2021）

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摘要

•The LPM offers a mechanism for the fluxionality of CO clusters.•[Ir4(CO)11PEt3] in the solid exists in two isomeric forms.•The fluxional behaviour of [Ir4(CO)11PEt3] can be rationalised by the LPM approach.

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关键词

Cluster,Carbonyl,Fluxionality

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