ChemInform Abstract: from Protected‐Hydroxy Acylsilanes to Functionalized Silyl Enol Ethers and Applications in Mukaiyama Aldol Reactions.

Johal Ruiz,Nagaraju Karre,Thierry Roisnel,Srivari Chandrasekhar,Rene Gree

ChemInform（2016）

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摘要

AbstractThe reaction of protected β‐hydroxy acylsilanes (I) and (XII) with sulfones provides (E)‐silyl enol ethers, whereas the reaction with Grignard reagent (V) give the (Z)‐isomers (VI) as sole products.

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Sulfonylation

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