Unprecedented β-manno type thiodisaccharides with a C-glycosylic function by photoinitiated hydrothiolation of 1-C-substituted glycals

Unique thiodisaccharides of β-manno type featuring C-glycosylic structure with an anomeric functional group for further elaboration were obtained by radical-mediated hydrothiolation of 1-C-acceptor-substituted glycals.