Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH₂P(CH₃)₂]C₆H₄)₃}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)

Dalton Transactions（2019）

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摘要

A relativistic quantum chemical study on hypothetical but potentially experimentally realisable TM–actinide and –neodymium complexes reveals the similarity in their structures but the differences in the multiplicity of the metal–metal bonds.

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Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH2P(CH3)2]C6H4)3}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)

Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH₂P(CH₃)₂]C₆H₄)₃}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)