New approaches to the functionalization of the 1-carba-closo-decaborate anion

Akim V Shmal'ko,Paula Cendoya,Sergey A Anufriev,Kyrill Yu Suponitsky,Detlef Gabel,Igor B Sivaev

Chemical Communications（2022）

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摘要

Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]− at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.

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