Palladium‐Catalyzed Oxalyl Amide‐Directed γ‐Arylation of Aliphatic Amines.

Jian Han,Yongxiang Zheng,Chao Wang,Yan Zhu,Daqing Shi,Runsheng Zeng,Zhi-Bin Huang,Yingsheng Zhao

ChemInform（2016）

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摘要

A method for palladium-catalyzed oxalyl amide-directed arylation of α-unsubstituted aliphatic amines with aryl iodides has been developed. A wide variety of aryl iodides are tolerated in this transformation, affording various γ-arylpropylamine derivatives. Heterocyclic iodides can also be competent reagents in this γ-C(sp(3))-H bonds transformation.

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关键词

aliphatic amines,cheminform abstract,palladium-catalyzed,amide-directed

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