Non‐Covalently Dendronized Flavins as Organocatalysts for Aerobic Reduction of Olefins.
ChemInform(2013)
摘要
Abstract A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure.
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关键词
dendronized flavins,aerobic reduction,organocatalysts,olefins,cheminform abstract,non-covalently
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