Direct Dehydrative Cross‐Coupling of Tautomerizable Heterocycles with Alkynes via Pd/Cu‐Catalyzed Phosphonium Coupling.

Fu-An Kang,James C. Lanter,Chaozhong Cai,Zhihua Sui,William V. Murray

ChemInform（2010）

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摘要

The first chemoselective direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes has been achieved via C–H/C–OH bond activations with direct C(sp2)–C(sp) bond formation, which is in line with ideal synthesis using readily available materials.

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