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Mechanism of halide exchange in reactions of CpRu(PPh3)2Cl with haloalkanes

Benjamin S. Rich,Noah B. Bissonnette, Alejandra Duran Balsa,Mulan Yang,Hope Meikle,Nithin Chintala,Sijia S. Dong,Rein U. Kirss

New Journal of Chemistry（2022）

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摘要
Kinetic measurements of the reaction between CpRu(PPh3)2Cl (1a) and 1-bromobutane reveal a nearly first order dependence on the concentration of haloalkane and a negative entropy of activation, ΔS† < 0.
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