Electrolyte Design Implications of Ion-Pairing in Low-Temperature Li Metal Batteries

John Holoubek,Kangwoon Kim,Yijie Yin,Zhaohui Wu,Haodong Liu,Mingqian Li,Amanda Chen,Hongpeng Gao,Guorui Cai,Tod A. Pascal,Ping Liu,Zheng Chen

Energy & environmental science（2022）

引用 65|浏览31

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摘要

The reversibility of Li metal batteries suffers beneath 0 °C due to a heightened charge-transfer barrier. Herein, the introduction of ion-pairs within the electrolyte is shown to improve this behavior, enabling hundreds of cycles down to −40 °C.

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