Conformational Properties of Hybrid Star-Shaped Polymers Comprised of Linear and Ring Arms.

We study the influence of arm architecture on the conformational properties of hybrid star-shaped macromolecules called rosette polymers containing linear and ring grafts connected to a central branching point in a good solvent regime. We utilize analytical methods and molecular dynamics simulations to determine the estimates for the relative size ratios of these polymers with respect to linear chains and starlike polymers composed of the same number of solely linear arms and equal molecular weights. The results of numerical simulations corroborate our theoretical prediction that rosette polymers undergo conformational compactification with increasing functionality of grafted rings. Our results quantitatively describe the impact of the complex architecture of the molecules with excluded volume on their effective size measures.