Effect of Tank-Mix Adjuvant on the Behavior of Chlorantraniliprole and Difenoconazole in Soil

In this study, both laboratory and field studies were performed to analyze the effect of the presence of tank-mixed methylated plant oil adjuvant on the adsorption and degradation of chlorantraniliprole (CAP) and difenoconazole (DIF) in soil. Adsorption kinetics and isotherms experiments were conducted according to the equilibrium oscillation method. Fourier transform infrared spectroscopy (FT-IR) analysis, soil contact angle, and zeta potential were used to research the interaction mechanism of adsorption. Fluorescence excitation emission matrix (FEEM) measurements were conducted to characterize soil dissolved organic matter. Field experiment was conducted to investigate the degradation of CAP and DIF combined with adjuvant. DIF exhibited a significantly higher Freundlich maximum adsorption capacity than CAP, which is consistent with the higher octanol-water partition coefficient of DIF. The sorption of CAP and DIF under laboratory conditions was significantly increased with the presence of adjuvant. Soils with high humic acids have strong adsorption capacity and contribute to significant adsorption of CAP and DIF. The half-lives of CAP and DIF tested in fluvo-aquic soil under field conditions were slightly reduced by the adjuvant. Adjuvant reduced the Groundwater Ubiquity Score (GUS) indices of CAP from 1.51 to 1.31, whereas that of DIF from 0.39 to 0.25. Combination between the pesticides and soil molecules can be enhanced, thereby promoting the adsorption and degradation of CAP and DIF in soil, and further reducing their potential to leach into groundwater when 0.1% methylated plant oil adjuvant was mixed and applied.