Enhanced degradation of sulfamethoxazole by microwave-activated peracetic acid under alkaline condition: Influencing factors and mechanism

Yinhao Dai,Chengdu Qi,Hui Cao,Yanni Wen,Yijie Zhao,Chenmin Xu,Shaogui Yang,Huan He

Separation and Purification Technology（2022）

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摘要

•Microwave enhances SMX degradation by PAA under alkaline condition.•Alkaline conditions are more favorable for SMX degradation in the MW/PAA system.•1O2, R–C• and •OH formed in the MW/PAA system and 1O2 is dominated under alkaline.•SMX degradation pathways were speculated based on byproducts identified by LC–MS.

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关键词

Peracetic acid,Microwave,Sulfamethoxazole,Singlet oxygen,Degradation mechanism,Toxicity assessment

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