Synthesis of aziridines by electrochemical oxidative annulation of chalcones with primary amines
TETRAHEDRON LETTERS(2021)
摘要
Synthesis of aziridines by electrochemical oxidative annulation of chalcone 1,3-diphenyl-2-propen-1-one with primary amines has been developed under external oxidant -and base-free conditions. The reaction constitutes a new transformation of chalcones with primary amines to aziridines, providing a complementary, simple, and environmentally friendly approach to the currently available methods. A reaction mechanism for this transformation has been proposed based on the cyclic voltammetry. (c) 2021 Published by Elsevier Ltd.
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关键词
Electrochemical oxidation, Annulation, Aziridines, Green chemistry
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