Asymmetric Synthesis of 1,2-Limonene Epoxides by Jacobsen Epoxidation
Pharmaceutical fronts(2021)
摘要
This study reported an asymmetric synthesis of 1,2-limonene epoxides. The absolute stereochemistry was controlled by a Jacobsen epoxidation of cis-1,2-limonene epoxide (with diastereomeric excess of 98%) and trans-1,2-limonene epoxide (with diastereomeric excess of 94%), which could be used as important raw materials for the preparation of related cannabinoid drugs.
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关键词
jacobsen epoxidation,1,2 limonene epoxides,asymmetric synthesis
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