Alloying Sb into all inorganic lead-free CsBi₃I₁₀ for improving the crystal growth and photovoltaic performance

Jian Kang,Shan Chen,Mengmeng Hao,Junxian Liu,Mohammad Al-Mamun,Porun Liu,Yun Wang,Huajie Yin,Huijun Zhao

Journal of Materials Chemistry A（2022）

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摘要

The incorporation of isovalent Sb3+ into all inorganic lead-free CsBi3I10 leads to the improved crystal growth and reduced bandgaps. Solar cells based on Cs(Bi0.7Sb0.3)3I10 yield a champion PCE of 1.54% with a high Voc of 0.81 V.

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Alloying Sb into all inorganic lead-free CsBi3I10 for improving the crystal growth and photovoltaic performance

Alloying Sb into all inorganic lead-free CsBi₃I₁₀ for improving the crystal growth and photovoltaic performance