Bis[cyclic (alkyl)(amino)carbene] isomers: Stable trans-bis(CAAC) versus facile olefin formation for cis-bis(CAAC)

Braulio M. Puerta Lombardi,Ethan R. Pezoulas,Roope A. Suvinen, Alexander Harrison,Zachary S. Dubrawski,Benjamin S. Gelfand,Heikki M. Tuononen,Roland Roesler

Chemical Communications（2022）

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摘要

A trans-bis(CAAC) was isolated and shown to be a ditopic ligand for rhodium and iridium. The cis-isomer is unstable towards intramolecular CC-bond formation, however, its formal insertion products into the bonds of H2O and NH3 were identified.

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