Cr3+ incorporation into an Al3+ Keggin-type oligomer to form the Al25.7Cr6.3S216+ polycation

Mohammad Shohel,Jack A. Smith,Tori Z. Forbes

Inorganic Chemistry Communications（2022）

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摘要

The partial hydrolysis of Al3+ solution by titrating with Cr3+ salt dissolved in KOH solution formed polycationic Keggin oligomer Al25.7Cr6.3S216+ (Al25.7Cr6.3O8(OH)60(H2O)28(SO4)2).

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关键词

Aluminum polycation,Keggin oligomer,Chromium substitution,X-ray diffraction

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