Inclusion of solvent polarizability in the modeling of ion-dipole mixtures within the mean spherical approximation (MSA)

Journal of Molecular Liquids(2022)

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摘要
•Solvent polarizability is included in a nonprimitive MSA model for electrolytes.•System: arbitrary mixture of hard ions and polar polarizable solvent molecules.•The thermodynamic properties are derived.•The obtained explicit formulas constitute a thermodynamically consistent set.
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关键词
Electrolytes,Polarizability,Non-primitive,Ion-dipole,Mean-spherical approximation (MSA)
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