Modification of the synthesis of layered titanium chloride nitride

Masashi Tanaka,Noriyuki Kataoka, Haruya Kobayashi,Masaya Fujioka,Masaru Oda,Aishi Yamamoto,Kensei Terashima,Junji Nishii,Hiromi Tanaka,Takayoshi Yokoya

Materials Research Bulletin（2022）

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摘要

•A synthesizing process of TiNCl has modified•The superconducting properties strongly depend on the synthesis temperature•Optical and photoemission spectroscopy revealed an in-gap state below the EF•Hydrogen emission was detected against the heat treatment of the obtained TiNCl•The in-gap state of hydrogen inhibits the introduction of electron carriers

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关键词

Nitride halides,Optical spectroscopy,Photoemission spectroscopy,Hydrogen incorporation,Superconductivity

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