Triazine 2D Nanosheets as a New Class of Nanomaterials: Crystallinity, Properties and Applications

Based on the recent (2015-2021) literature data, the authors analyze the mutual dependence of crystallinity/amorphism and specific surface area and porosity in covalent triazine frameworks (CTFs), taking into account thermodynamic and kinetic control in the synthesis of these 2D nanosheets. CTFs have now become a promising new class of high-performance porous organic materials. They can be recycled and reused easily, and thus have great potential as sustainable materials. For 2D CTFs, numerous examples are given to support the known rule that the structure and properties of any material with a given composition depend on the conditions of its synthesis. The review may be useful for elder students, postgraduate students, engineers and research fellows dealing with chemical synthesis and modern nanotechnologies based on 2D covalent triazine frameworks.