MOF Pillaring Method: Ligand-to-Ligand and Axial-to-Axial Cross-Linking of "Paddlewheels"

Mingxing Zhang,Penghui Liu,Rui Dang,Peipei Zhang,Huihui Cui, Lifang Zhang,Guomin Jiang,Jin Wang,Miao Wang,Tongming Sun,Minmin Wang,Guoping Qin,Yanfeng Tang,Su Wang

INORGANIC CHEMISTRY（2022）

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摘要

By shortening the previous shortest tetracarboxylate ligand, the first ligand-to-ligand and axial-to-axial pillaring method was realized in the prototype MOF NTUniv-56 (NTUniv = Nantong University), which exhibit a rare (2,4,6)-connected net with a new topology and interesting gas adsorption performance.

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