Insight into weakly antiferromagnetic coupling behavior in a non-integer oxidation state bis(2-thioxo-1,3-dithiole-4,5- dithiolate)nickelate molecular semiconductor

Inorganic Chemistry Communications(2022)

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摘要
In (ImH)[Ni(dmit)2]2, the [Ni(dmit)2]0.5− anions form dimeric stack, and the weakly AFM couplings between anion dimers are achieved through magnetic dipole–dipole interactions.
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关键词
2-Thioxo-1,3-dithiole-4,5-dithiolate complex,Radical,Non-integer oxidation state,Magnetism,Conduction
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