Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp(3))-P Bond Formation

Cheng-Kun Li,Ze-Kun Tao,Adedamola Shoberu,Wei Zhang,Jian-Ping Zou

ORGANIC LETTERS（2022）

引用 11|浏览3

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摘要

A Cu-I-catalyzed cross-coupling of alkyl-and phosphorus-centered radicals for C(sp(3))-P bond formation is introduced. Diacyl peroxides, generated in situ from aliphatic acids and H2O2, serve as a source for alkyl radicals and also an initiator for the generation of phosphorus radicals from H-P(O) compounds.

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