Aurophilic interaction leads to distortion of the ten-membered centrosymmetric Au2As2S2C4 ring in [Au2{μ-(SC6H4-2-AsPh2)-κS,κAs}2]

Alexandra Hildebrand,Peter Lonnecke,Luminita Silaghi-Dumitrescu,Evamarie Hey-Hawkins

Polyhedron（2022）

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摘要

A dinuclear gold complex, [Au2{μ-(SC6H4-2-AsPh2)-κS,κAs}2], with a ten-membered centrosymmetric Au2As2S2C4 ring was structurally characterised (C: dark grey, H: grey, As: red, S: yellow, Au: brown).

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关键词

Heterotopic ligand,Dinuclear complex,Gold,Dimer

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