Simple synthesis of energetic ferrocene‐based coordination derivatives as attractive multifunctional catalysts for the thermal decomposition of ammonium perchlorate

Four novel energetic ferrocene-based coordination derivatives, namely [M (FcHz)center dot(NO3)](n) (M = Co2+, Cu2+, Zn2+, and Fe3+), were successfully prepared through a solvothermal method using 1,1 '-bis(1-hydrazinoethylene) ferrocene (FcHz) with excellent electron transfer ability and energy bonds (C=N, N-N) as a ligand to coordinate with transition metals with high catalytic activity to promote the decomposition of ammonium perchlorate (AP). Their chemical structure, crystalline features, and morphology were comprehensively characterized, and their catalytic performance was analyzed. It is found that all [M (FcHz)center dot(NO3)](n) exhibited better catalytic performance for AP decomposition than that of traditional catalyst catocene because of the optimal synergistic effect between FcHz and transition metals. In addition, they had a large specific surface area, strong NH3 absorption capacity, and high thermal property, which also could accelerate AP decomposition. [Co (FcHz)center dot(NO3)](n) was the best one, and AP with [Co (FcHz)center dot(NO3)](n) could decrease the high-temperature decomposition temperature and apparent activation energy of AP decomposition by 110 degrees C and 75.82 kJ mol(-1), respectively, and increase heat release by 1066 J/g. The online thermogravimetric analyzer-coupled with a Fourier-transform infrared explored the AP decomposition products at different temperatures catalyzed by [Co (FcHz)center dot(NO3)](n), and a possible catalytic mechanism was also proposed. The results indicate that [Co (FcHz)center dot(NO3)](n) with high efficiency, high energy, and high anti-migration has application prospects in AP-based solid propellants.