Supported-Pd catalyzed carbonylative synthesis of phthalimides and isoindolinones using Oxalic acid as in situ CO surrogate with 2-iodobenzamides and 2-iodobenzylanilines in ppm-level catalyst loading

Shankar Ram,Pushkar Mehara,Ashish Kumar,Ajay Kumar Sharma,Arvind Singh Chauhan,Ajay Kumar,Pralay Das

Molecular Catalysis（2022）

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摘要

•Novel approach for phthalimides and isoindolin-1-ones synthesis.•PPM (2000–3000) level catalyst is enough for reaction.•Devoid the need of external base and additives.•Successfully applied for 1.5 gram scale reaction.•Vast substrate scope (57 examples)

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关键词

Supported palladium,2-Iodobenzamides,2-Iodobenzylanilines,Phthalimides,Isoindolinones and Oxalic acid

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