Thermodynamic Properties of Selected Glasses in the CaO–Al2O3–TiO2 System

Anatoly S. Arkhipin,Alexander Pisch,Georgii M. Zhomin,Semen V. Kuzovchikov,Alexandra V. Khvan,Natalia N. Smirnova,Alexey V. Markin,Nikita A. Kovalenko,Irina A. Uspenskaya

JOURNAL OF NON-CRYSTALLINE SOLIDS（2023）

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摘要

•Experimental thermodynamic study of selected glasses in the CaO–Al2O3–TiO2 system.•No impact of TiO2 addition on the heat capacity of a Ca12Al14O33 glass up to 7 wt%.•A negative enthalpy of mixing of glassy Ca12Al14O33 with TiO2.

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关键词

Calcium aluminate,Calcium aluminotitanate,C12A7,Heat capacity,Heat content,Enthalpy of formation

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