Electrochemical quinuclidine-mediated C–H activation: Intermediates and mechanism

Filip Vorobjov,Gilles De Smet,Nick Daems,H. Y. Vincent Ching,Pieter Leveque,Bert U. W. Maes,Tom Breugelmans

Journal of Electroanalytical Chemistry（2022）

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摘要

•Hydrogen Peroxide is the terminal oxidant in the reaction.•Quinuclidine is oxidized by hydrogen peroxide to quinuclidine N-oxide.•1,1,1,3,3,3-hexafluoropropan-2-ol is consumed during oxygen reduction and oxidation to 1,1,1,3,3,3-hexafluoroacetone.•0.1 M 1,1,1,3,3,3-hexafluoropropan-2-ol is optimal for quinuclidine’s oxidation.

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关键词

Electrochemical C–H activation,Analytical electrochemistry,ORR,Hydrogen peroxide,Quinuclidine N-oxide,RVC corrosion

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