Efficient one-pot synthesis of the unexpected fused multicyclic iminosugars by an aza-Diels-Alder mechanism

Jilai Wu,Lulu Su,Tongguan Jia,Xiaoming Xu,Yaxin Cui,Chao Wei,Xiaoliu Li,Hua Chen

ORGANIC CHEMISTRY FRONTIERS（2022）

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摘要

A simple and efficient one-pot synthesis has been developed firstly by an aza-Diels-Alder mechanism for the stereoselective synthesis of novel fused multicyclic iminosugars with structural diversity. The adaptability of this method has been demonstrated by using a variety of aromatic amines and tosylated sugars.

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关键词

multicyclic iminosugars,synthesis,one-pot,aza-diels

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