Observation of collectivity enhanced magnetoassociation of ⁶Li in the quantum degenerate regime

The association process of Feshbach molecules is well described by a Landau-Zener (LZ) transition above the Fermi temperature, such that two-body physics dominates the dynamics. However, using Li-6 atoms and the associated Feshbach resonance at B (r) = 834.1 G, we observe an enhancement of the atom-molecule coupling as the fermionic atoms reach degeneracy, demonstrating the importance of many-body coherence not captured by the conventional LZ model. In the experiment, we apply a linear association ramp ranging from adiabatic to non-equilibrium molecule association for various temperatures. We develop a theoretical model that explains the temperature dependence of the atom-molecule coupling. Furthermore, we characterize this dependence experimentally and extract the atom-molecule coupling coefficient as a function of temperature, finding qualitative agreement between our model and experimental results. In addition, we simulate the dynamics of molecular association during a nonlinear field ramp. We find that, in the non-equilibrium regime, molecular association efficiency can be enhanced by sweeping the magnetic field cubically with time. Accurate measurement of the atom-molecule coupling coefficient is important for both theoretical and experimental studies of molecular association and many-body collective dynamics.