Towards Panchromatic Fe(ii) NHC Sensitizersviahomo Inversion

Anil Reddy Marri,Bogdan Marekha,Thomas Penfold,Stefan Haacke,Philippe C. Gros

Inorganic chemistry frontiers（2023）

引用 2|浏览20

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摘要

Fused polythiophenes attached to Fe(ii)NHC complexes induced a mixing of the t2gand π HOMO orbitals promoting 80 nm red-shift of the MLCT transition, 3 fold increase of the molar extinction coefficient and3MLCT excited state lifetime up to 18 ps.

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